Issue 1, 1979

X-Ray crystal structure of tetra-antimony(V) tridecachloride heptafluoride, (Sb2Cl6.5F3.5)2

Abstract

The title compound has been prepared and characterised by single-crystal X-ray crystallography. Crystals are monoclinic with a= 12.921(4), b= 7.423(4), c= 12.921(4)Å, β= 90.10(3), and Z= 4. The structure has been refined in the non-standard space group I2 to give a final agreement index R′ of 0.116 for 1 129 independent reflections. The structure consists of cis-fluorine-bridged tetramers of SbCl3F2 with two antimony atoms having a chlorine atom partially substituted by fluorine. The problem of disorder in the SbClxF5 –x species is discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1979, 62-65

X-Ray crystal structure of tetra-antimony(V) tridecachloride heptafluoride, (Sb2Cl6.5F3.5)2

J. G. Ballard, T. Birchall and D. R. Slim, J. Chem. Soc., Dalton Trans., 1979, 62 DOI: 10.1039/DT9790000062

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