It is shown that the mechanism of metal migration in [M(CO)3(η6-C8H8)](M = Cr or W) is a combination of 1,2- and 1,3-shifts. The mechanisms of both this migration and also that found for [Cr(CO)3(η6-C8H4Me4-1,3,5,7)] are explained.
J. A. Gibson and B. E. Mann, J. Chem. Soc., Dalton Trans., 1979, 1021 DOI: 10.1039/DT9790001021
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