η-Cyclopentadienylcobalt chemistry: allylic, alkyl, and hydrido-derivatives
Abstract
The new complexes [Co(η-C5H5)(η-2-MeC3H4)L][PF6](L = CO, PMe3, C5H5N, or NH3), [Co(η-C5H5)(η-1-MeC3H4)L′][PF6] and [Co(η-C5H5)(η-C3H5)L′][PF6](L′= CO or PMe3), [Co(η-C5H5)(η-2-MeC3H4)I], [Co(η-C5H5)(PMe3)(CO)], [Co(η-C5H5)(PMe3)3][PF6]2, [Co(η-C5H5)(PMe2Ph)I2], [Co(η-C5H5)(PMe2Ph)2H][PF6], and [Co(η-C5H5)(PMe3)Me2] have been prepared and characterized.