Ruthenium metal prepared by NaBH4-reduction of RuO2 possesses unique activity in consistently catalysing hydrogen isotope exchange between organosilanes and C6D6., exchange occurring readily in alkul and aryl positions, particularly in trisubstituted silanes; a modification of the technique can also be used for the tritium labelling of these silanes.
J. L. Garnett, M. A. Long and P. Sriwattanatamma, J. Chem. Soc., Chem. Commun., 1981, 844 DOI: 10.1039/C39810000844
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