Issue 16, 1981

X-Ray crystal structure of [N(CH2CH2PPh2)3]2Co2(µ-Hg2); the dimeric Hg22+ ion forms a linear bridge between the two cobalt atoms

Abstract

The reaction of [(np3)CoCl]BPh4{np3=[N(CH2CH2PPh2)3]} with sodium amalgam gives the tetrametallic complex (np3)Co(µ-Hg2)Co(np3).thf (thy = tetrahydrofuran) the X-ray structural analysis of which shows that the Hg22+ ion linearly bridges two Co(np3) moieties.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 865-866

X-Ray crystal structure of [N(CH2CH2PPh2)3]2Co2(µ-Hg2); the dimeric Hg22+ ion forms a linear bridge between the two cobalt atoms

C. A. Ghilardi, S. Midollini and S. Moneti, J. Chem. Soc., Chem. Commun., 1981, 865 DOI: 10.1039/C39810000865

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