Issue 20, 1981

PdII-catalysed isomerisations of 3-acetoxy-1,4-dienes to 1-acetoxy-2,4-dienes: stereochemical and preparative aspects

Abstract

The rapid PdII-catalysed rearrangement of 3-acetoxy-1,4-dienes to 1-acetoxy-2,4-dienes [e.g.(2E,5Z)-4-acetoxydeca-2,5-diene →(3E,5Z)-2-acetoxydeca-3,5-diene (ca. 80%)] occurs in stereoselective and regio-selective manner.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1030-1031

PdII-catalysed isomerisations of 3-acetoxy-1,4-dienes to 1-acetoxy-2,4-dienes: stereochemical and preparative aspects

B. T. Golding, C. Pierpoint and R. Aneja, J. Chem. Soc., Chem. Commun., 1981, 1030 DOI: 10.1039/C39810001030

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements