By 2H n.m.r. spectroscopy it is shown that, during the conversion of cis-aconitic acid (1) into itaconic acid (2), the proton coming from the medium is introduced at C-2 of (1) on the 2-re,3-si face.
B. M. Ranzi, F. Ronchetti, G. Russo and L. Toma, J. Chem. Soc., Chem. Commun., 1981, 1050 DOI: 10.1039/C39810001050
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