The oxazaphosph(v)ole (1) reacts with neat carbonyl compounds (aldehydes, ketones and formamides) to give the phosphinates (2); in solution, a benzoxazole is formed in one case.
J. I. G. Cadogan, J. B. Husband and H. McNab, J. Chem. Soc., Chem. Commun., 1981, 1054 DOI: 10.1039/C39810001054
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