Evidence for secondary building unit effects on the solid state 29Si n.m.r. resonance of silicon in zeolitic structures
Abstract
Zeolites which contain five-membered rings of silica tetrahedra (HZ mordenite, Na-ZSM-5, and H-ZSM-11) present a 29Si-n.m.r. line at ca.–113 p.p.m. in contrast with other zeolites which do not contain this building unit (Na-A, Na-X, Na-Y, and H-L), for which resonance occurs in the –80 to –106 p.p.m. range, depending on the Si:Al ratio.