Generation and reactivity of 4-azatricyclo[5.3.1.13,9]dodec-3-ene and 5-azatricyclo[4.4.1.13,9]dodec-5-ene, new bridgehead imines
Abstract
The title bridgehead imines have been generated in a ratio of 1 : 2 by photolysis of 3-azidohomoadamantane; their chemical reactivity is described.