An example of intramolecular cyclisation of a crowded phosphinic chloride via loss of hydrogen chloride and formation of a phosporus–carbon bond is described; unexpected cleavage of an acyclic phosphorus-carbon bond is also reported.
A. Baceiredo, G. Bertrand, P. Mazerolles and J. Majoral, J. Chem. Soc., Chem. Commun., 1981, 1197 DOI: 10.1039/C39810001197
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