The stereodynamic behaviour of the complexes [Fe3(CO)11L][L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12](M = Co, Rh, or lr) and their derivatives.
R. E. Benfield, P. D. Gavens, B. F. G. Johnson, M. J. Mays, S. Aime, L. Milone and D. Osella, J. Chem. Soc., Dalton Trans., 1981, 1535 DOI: 10.1039/DT9810001535
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