It is shown that the rearrangement of platinacyclobutanes to platinum–alkene complexes occurs by a mechanism involving an initial 1,3-H shift (α-elimination) rather than a 1,2-H shift (β-elimination) as reported previously.
S. S. M. Ling and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1982, 412 DOI: 10.1039/C39820000412
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