Primary and secondary deuterium isotope effects and calculated primary isotope effects for the 2-pyridone-catalysed mutarotation of tetramethylglucose suggest rate-limiting simultaneous transfer of two protons coupled with considerable heavy atom motion.
K. Engdahl, H. Bivehed, P. Ahlberg and W. H. Saunders, J. Chem. Soc., Chem. Commun., 1982, 423 DOI: 10.1039/C39820000423
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