Issue 17, 1982

The synthesis and X-ray crystal structure of [MoW2(µ-CR)2(µ-CO)2(CO)4(η-C5H5)2](R = C6H4Me-4), [N(PPh3)2][W2(µ-CHR)(CO)7(η-C5H5)], [AuW(µ-CHR)(CO)2(PPh3)(η-C5H5)], and [W = CHR(SnPh3)(CO)2-(η-C5H5)]

Abstract

The Structures of the compounds [MoW2(µ-CR)2(µ-CO)2-(CO)4(η-C5H5)2](R = C6H4Me-4), [N(PPh3)2]-[W2(µ-CHR)(CO)7(η-C5H5)], [AuW(µ-CHR)(CO)2(PPh3)(η-C5H5)], and [W = CHR(SnPh3)(CO)2-(η-C5H5)] have been established by single-crystal X-ray diffraction, following their synthesis from [W [triple bond, length half m-dash] CR(CO)2-(η-C5H5)] and the appropriate reagents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1006-1008

The synthesis and X-ray crystal structure of [MoW2(µ-CR)2(µ-CO)2(CO)4(η-C5H5)2](R = C6H4Me-4), [N(PPh3)2][W2(µ-CHR)(CO)7(η-C5H5)], [AuW(µ-CHR)(CO)2(PPh3)(η-C5H5)], and [W = CHR(SnPh3)(CO)2-(η-C5H5)]

G. A. Carriedo, D. Hodgson, J. A. K. Hooward, K. Marsden, F. G. A. Stone, M. J. Went and P. Woodward, J. Chem. Soc., Chem. Commun., 1982, 1006 DOI: 10.1039/C39820001006

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