The oxidative rearrangement of O,O′-diacyl derivatives of leucoindigo with dichlorodicyanobenzoquinone in dimethyl sulphoxide affords N,N′-diacyl derivatives of indigotin in high yield; it has been found that the heat of cis-to-trans isomerization in acetonitrile for N,N′-bis (phenylacetyl) indigotin is 29.9 kcal mol–1(60 cal g–1).
J. Setsune, H. Wakemoto, K. Matsukawa, S. Ishihara, R. Yamamoto and T. Kitao, J. Chem. Soc., Chem. Commun., 1982, 1022 DOI: 10.1039/C39820001022
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...