Polymerization of racemic 1-methylbicyclo[2.2.1]hept-2-ene(1) using ReCl5 as catalyst yields an alternating ring-opened copolymer of the two enantiomers, with an all-cis, head-tail, syndiotactic structure as revealed by the 13C n.m.r. spectrum of the polymer and its hydrogenated product.
J. G. Hamilton, K. J. Ivin, J. J. Rooney and L. C. Waring, J. Chem. Soc., Chem. Commun., 1983, 159 DOI: 10.1039/C39830000159
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