A 1,3-silyl group shift from carbon to oxygen occurs readily when β-hydroxyvinylsilanes are treated with catalytic amounts of sodium hydride in hexamethylphosphoric triamide, thus providing the first demonstration of the rearrangement of silicon from sp2-carbon to oxygen.
F. Sato, Y. Tanaka and M. Sato, J. Chem. Soc., Chem. Commun., 1983, 165 DOI: 10.1039/C39830000165
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