The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.
M. J. McGlinchey, J. L. Fletcher, B. G. Sayer, P. Bougeard, R. Faggiani, C. J. L. Lock, A. D. Bain, C. Rodger, E. P. Kündig, D. Astruc, J. Hamon, P. Le Maux, S. Top and G. Jaouen, J. Chem. Soc., Chem. Commun., 1983, 634 DOI: 10.1039/C39830000634
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