Issue 11, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation, characterization and X-ray crystal structure of Ru2H6N2(PPH3)4, a compound containing four bridging hydrides and a ruthenium–ruthenium double bond

Bruno Chaudret,   Jean Devillers  and  René Poilblanc  

Abstract

The compound obtained by recrystallisation under N2 of the hydrogenation product of Ru(styrene)2(PPh3)2 has been shown to be Ru2H6N2(PPh3)4, a compound containing four bridging hydrides and a short Ru–Ru distance which is consistent with a metal–metal doubel bond; 1H and 31P n.m.r. spectra have allowed us to propose that the crude hydrogenation product is a mixture of RuH6(PPh3)2 and Ru2H8(PPh3)4.

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Article information

DOI
https://doi.org/10.1039/C39830000641
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 641-643

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Preparation, characterization and X-ray crystal structure of Ru2H6N2(PPH3)4, a compound containing four bridging hydrides and a ruthenium–ruthenium double bond

B. Chaudret, J. Devillers and R. Poilblanc, J. Chem. Soc., Chem. Commun., 1983, 641 DOI: 10.1039/C39830000641

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