In the biosynthesis of echinulin (1) the pro-S methyl of the 1,1-dimethylallyl group is derived predominantly (89%) from the methyl group of mevalonic acid.
D. M. Harrison and P. Quinn, J. Chem. Soc., Chem. Commun., 1983, 879 DOI: 10.1039/C39830000879
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