Dinitrogen forms a push–pull stabilized double bond [125.2(6) pm] when one end is bound to an electron-rich cobalt complex and the other end is part of an N2Al2 ring in the (Me3P)3 CoN2AlMe2 dimer, the structure of which has been found by X-ray crystallography.
H. F. Klein, K. Ellrich and K. Ackermann, J. Chem. Soc., Chem. Commun., 1983, 888 DOI: 10.1039/C39830000888
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