Issue 16, 1983

Formation of η6-pyridine complexes of molybdenum (0) by a σ to π rearrangement in Mo(N2)2(NC5H4-4-R)(PMePh2)3, R[double bond, length half m-dash]H, Me

Abstract

The new complexes trans,mer-Mo(N2)2(NC5H4-4-R)(PMePh2)3, R[double bond, length half m-dash]H, Me lose dinitrogen in Vacuo at 25 °C in arene solvents to give Mo(η6-NC5H4R)(PMePh2)3, the first stable η6-pyridine complexes of molybdenum.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 909-910

Formation of η6-pyridine complexes of molybdenum (0) by a σ to π rearrangement in Mo(N2)2(NC5H4-4-R)(PMePh2)3, R[double bond, length half m-dash]H, Me

R. H. Morris and J. M. Ressner, J. Chem. Soc., Chem. Commun., 1983, 909 DOI: 10.1039/C39830000909

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