The stereochemistry of the 1,2-H shift of photolytically generated benzylchlorocarbene is significantly affected by aryl substituents and by the addition of an alkene.
H. Tomioka, N. Hayashi, Y. Izawa and M. T. H. Liu, J. Chem. Soc., Chem. Commun., 1984, 476 DOI: 10.1039/C39840000476
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