The thermal rearrangement of a chiral αβ-epoxyketone is concerted process that proceeds without loss of optical activity and with inversion of configuration at the migration terminus.
R. D. Bach and J. M. Domagala, J. Chem. Soc., Chem. Commun., 1984, 1472 DOI: 10.1039/C39840001472
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