Issue 22, 1984

Biosynthesis of the meroterpenoid metabolite, andibenin B: incorporation of sodium [1-13C, 18O2]acetate and 18O2

Abstract

Incorporation of sodium [1-13C, 18O2]acetate and 18O2 gas into andibenin B (1) by cultures of Aspergillus variecolor and observation of 18O isotope-induced shifts in the 13C n.m.r. spectra of the enriched metabolites establish the origins of all the oxygen atoms and provide mechanistic information on the biosynthetic pathway.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1498-1499

Biosynthesis of the meroterpenoid metabolite, andibenin B: incorporation of sodium [1-13C, 18O2]acetate and 18O2

C. R. McIntyre, T. J. Simpson, R. N. Moore, L. A. Trimble and J. C. Vederas, J. Chem. Soc., Chem. Commun., 1984, 1498 DOI: 10.1039/C39840001498

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