Issue 22, 1984

Structural determination of a cobalt(III) complex with a Co to tertiary carbon bond: how long can a Co–C bond be?

Abstract

The compound trans-adamantylbis(dimethylglyoximato)(1-methylimidazole)cobalt(III), which has the longest accurately determined Co–C bond of 2.154(5)Å, is the first structurally characterized organocobalt B12 model compound with Co to tertiary carbon bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1508-1510

Structural determination of a cobalt(III) complex with a Co to tertiary carbon bond: how long can a Co–C bond be?

N. Bresciani-Pahor, L. G. Marzilli, L. Randaccio, P. J. Toscano and E. Zangrando, J. Chem. Soc., Chem. Commun., 1984, 1508 DOI: 10.1039/C39840001508

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