Issue 22, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Unprecedented higher stability of E-than Z-olefin complexes of platinum(II). Molecular structures of the η3-methally(triphenylphosphine)(Z-and E-but-2-ene)-platinum(II) cation

Kunio Miki,   Kazuhiko Yamatoya,   Nobutami Kasai,   Hideo Kurosawa,   Mitsuhiro Emoto  and  Akira Urabe  

Abstract

The C[double bond, length half m-dash]C bond of Z-but-2-ene in one of the title complexes lies almost in the co-ordination plane, while that of the corresponding E-but-2-ene complex, which unprecedentedly is more stable in solution than the former, forms and angle of 67° with the plane.

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Article information

DOI
https://doi.org/10.1039/C39840001520
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1520-1522

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Unprecedented higher stability of E-than Z-olefin complexes of platinum(II). Molecular structures of the η3-methally(triphenylphosphine)(Z-and E-but-2-ene)-platinum(II) cation

K. Miki, K. Yamatoya, N. Kasai, H. Kurosawa, M. Emoto and A. Urabe, J. Chem. Soc., Chem. Commun., 1984, 1520 DOI: 10.1039/C39840001520

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