The carbene selectivity index mcxy for perchlorovinylcarbene [Cl2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CClC(Cl):] was determined by competition experiments with different substituted olefins as ∼0.38, whereas the value calculated from Moss's equation is 0.34 ± 0.1; this proves at least qualitatively that perchlorovinylcarbene is an electrophilic carbene.
R. Kostikov and A. de Meijere, J. Chem. Soc., Chem. Commun., 1984, 1528 DOI: 10.1039/C39840001528
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