EXAFS analysis of the pyrolysis product of [(µ-H)Os3(CO)10{µ-S[CH2]3Si(OMe)3–x(O-silica)x}] shows the average co-ordination sphere of osmium contains O, S, and Os at bonding distances in addition to carbonyl groups; in contrast there is little evidence of phosphorus co-ordination on pyrolysis of [(µ-H)Os3H(CO)10–{PPh2[CH2]2Si(OEt)3–x(O-silica)x}].
N. Binsted, S. L. Cook, J. Evans and G. N. Greaves, J. Chem. Soc., Chem. Commun., 1985, 1103 DOI: 10.1039/C39850001103
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