Very high enantio- and diastereo-selective synthesis of certain amino acids may be realized through the reaction of 9-allyl- and 9-but-2-enyl-9-borabicyclo[3.3.1]nonane with α-imino-esters.
Y. Yamamoto, W. Ito and K. Maruyama, J. Chem. Soc., Chem. Commun., 1985, 1131 DOI: 10.1039/C39850001131
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