Enamides (3)–(6) have been hydrogenated with enantiomeric excesses up to 88% in aqueous–organic two-phase solvent systems by rhodium complexes of sulphonated chiral bisphosphines.
F. Alario, Y. Amrani, Y. Colleuille, T. P. Dang, J. Jenck, D. Morel and D. Sinou, J. Chem. Soc., Chem. Commun., 1986, 202 DOI: 10.1039/C39860000202
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