At room temperature, silacyclopentyl radicals exchange hydrogen or deuterium reversibly with the C–H or C–D bonds of adamantane in a matrix causing specific deuteriation or de-deuteriation at ![[double bond splayed left]](https://www.rsc.org/images/entities/char_e009.gif)
Si–H or Si–D bonds in the radical.
R. A. Jackson and A. K. Zarkadis, J. Chem. Soc., Chem. Commun., 1986, 205 DOI: 10.1039/C39860000205
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