Issue 3, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel ruthenium(V) dioxo complexes: synthesis, characterization, and reactivity of trans-[RuV(tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

Chi-Ming Che  and  Kwok-Yin Wong  

Abstract

trans-[RuV(tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been generated by electrochemical reduction of trans-[RuVI(tmc)(O)2](ClO4)2 in acetonitrile; it is paramagnetic (µeff.= 1.98 µB) and rapidly disproportionates into trans-[RuVI(tmc)(O)2]2+ and trans-[RuIV(tmc)(O)(OH2)]2+ upon dissolution in aqueous acidic solution.

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Article information

DOI
https://doi.org/10.1039/C39860000229
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 229-230

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Novel ruthenium(V) dioxo complexes: synthesis, characterization, and reactivity of trans-[RuV(tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

C. Che and K. Wong, J. Chem. Soc., Chem. Commun., 1986, 229 DOI: 10.1039/C39860000229

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