Issue 3, 1986

Biosynthesis of 1-aminocyclopropanecarboxylic acid: steric course of the reaction at the α-position

Abstract

By using a regiospecifically dideuteriated form of the substrate it is shown that the enzymic conversion of (S)-adenosylmethionine (SAM) into 1-aminocyclopropanecarboxylic acid (ACC) involves an inversion at the α-carbon centre, a feature rarely observed for other pyridoxal phosphate-dependent reactions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 238-239

Biosynthesis of 1-aminocyclopropanecarboxylic acid: steric course of the reaction at the α-position

R. Wiesendanger, B. Martinoni, T. Boller and D. Arigoni, J. Chem. Soc., Chem. Commun., 1986, 238 DOI: 10.1039/C39860000238

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