Issue 22, 1986

Synthesis and enantiomer recognition of crown ethers containing the cis-4b,5,6,10b,11,12-hexahydrochrysene and the cis-4b,5,9b,10-tetrahydroindeno[2,1-a]-indene subunit as the chiral centre

Abstract

The absolute configurations of the diols (–)-(1) and (+)-(4) of C2 symmetry have been established and the enantiomer recognition behaviour of the novel optically active crown ethers (–)-(3) and (+)-(6) prepared from (–)-(1) and (+)-(4), respectively, has been examined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1675-1676

Synthesis and enantiomer recognition of crown ethers containing the cis-4b,5,6,10b,11,12-hexahydrochrysene and the cis-4b,5,9b,10-tetrahydroindeno[2,1-a]-indene subunit as the chiral centre

K. Naemura, M. Komatsu, K. Adachi and H. Chikamatsu, J. Chem. Soc., Chem. Commun., 1986, 1675 DOI: 10.1039/C39860001675

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