Issue 11, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reaction of nitrobenzene with [M3(CO)12](M = Fe or Ru) in the presence of [Co2(CO)8]: isolation and structure of [Ru3(CO)7(NPh)(η6-C6H6)]

Amitabha Basu,   Sumit Bhaduri,   Hanif Khwaja,   Peter G. Jones,   Karen Meyer-Bäse  and  George M. Sheldrick  

Abstract

The complexes [Ru3(CO)7(NPh)(C6H6)](1) and [FeCo2(CO)9(NPh)](2) are formed in the reactions between PhNO2 and [M3(CO)12](M = Ru or Fe) only when [Co2(CO)8] is present. The structure of (1) has been determined by X-ray diffraction; it contains triply bridging CO and PhN ligands and an η6-benzene ligand co-ordinated to only one metal atom.

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Article information

DOI
https://doi.org/10.1039/DT9860002501
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 2501-2503

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Reaction of nitrobenzene with [M3(CO)12](M = Fe or Ru) in the presence of [Co2(CO)8]: isolation and structure of [Ru3(CO)7(NPh)(η6-C6H6)]

A. Basu, S. Bhaduri, H. Khwaja, P. G. Jones, K. Meyer-Bäse and G. M. Sheldrick, J. Chem. Soc., Dalton Trans., 1986, 2501 DOI: 10.1039/DT9860002501

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