A hydroperoxo–dicopper(II) complex (3) can be prepared by (a) direct protonation of a peroxo–dicopper(II) complex (2), (b) oxygenation of a ligand-protonated form of the dicopper(I) precursor of (2), and (c) reaction of hydrogen peroxide with a hydroxo-bridged dicopper(II) complex (5); (3) reacts quantitatively with triphenylphosphine or tetrahydrothiophene to give (5) and oxygenated products.
K. D. Karlin, R. W. Cruse and Y. Gultneh, J. Chem. Soc., Chem. Commun., 1987, 599 DOI: 10.1039/C39870000599
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