Issue 12, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of a trimethyldihydroperimidinium cation from proton sponge [1,8-bis(dimethylamino)naphthalene] during base-promoted reactions of rhodium and ruthenium complexes

Sujatha N. Gamage,   Robert H. Morris,   Steven J. Rettig,   David C. Thackray,   Ian S. Thorburn  and  Brian R. James  

Abstract

Proton sponge, in the presence of mer-RhCl3(dmso)3 or [RuCl(dppb)]2(µ-Cl)3(dmso = dimethyl sulphoxide, dppb = Ph2P[CH2]4PPh2), generates (via a net hydride loss from one methyl group) the 1,1,3-trimethyl-2,3-dihydroperimidinium cation, which is isolated as the counter-ion in complexes containing the anions trans-[RhCl4(dmso)2]– and {[RuCl(dppb)]2(µ-Cl)3}–.

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Article information

DOI
https://doi.org/10.1039/C39870000894
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 894-895

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Formation of a trimethyldihydroperimidinium cation from proton sponge [1,8-bis(dimethylamino)naphthalene] during base-promoted reactions of rhodium and ruthenium complexes

S. N. Gamage, R. H. Morris, S. J. Rettig, D. C. Thackray, I. S. Thorburn and B. R. James, J. Chem. Soc., Chem. Commun., 1987, 894 DOI: 10.1039/C39870000894

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