Remarkable carbonylation of a co-ordinated phospha-alkyne ButCP to afford the novel phosphinidene ligand ButC(CO)P, crystal and molecular structure of [Re2(CO)8Pt(dppe){ButC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)

Saud I. Al-Resayes; Peter B. Hitchcock; John F. Nixon

doi:10.1039/C39870000928

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Remarkable carbonylation of a co-ordinated phospha-alkyne Bu^tCP to afford the novel phosphinidene ligand Bu^tC(CO)P, crystal and molecular structure of [Re₂(CO)₈Pt(dppe){Bu^tC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)

Saud I. Al-Resayes, Peter B. Hitchcock and John F. Nixon

Abstract

An unusual carbonylation of a co-ordinated phospha-alkyne to give a phosphinidine is reported.

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DOI: https://doi.org/10.1039/C39870000928
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1987, 928-929

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Remarkable carbonylation of a co-ordinated phospha-alkyne Bu^tCP to afford the novel phosphinidene ligand Bu^tC(CO)P, crystal and molecular structure of [Re₂(CO)₈Pt(dppe){Bu^tC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)

S. I. Al-Resayes, P. B. Hitchcock and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1987, 928 DOI: 10.1039/C39870000928

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Journal of the Chemical Society, Chemical Communications

Remarkable carbonylation of a co-ordinated phospha-alkyne Bu^tCP to afford the novel phosphinidene ligand Bu^tC(CO)P, crystal and molecular structure of [Re₂(CO)₈Pt(dppe){Bu^tC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)

Abstract

Article information

Download Citation

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Remarkable carbonylation of a co-ordinated phospha-alkyne Bu^tCP to afford the novel phosphinidene ligand Bu^tC(CO)P, crystal and molecular structure of [Re₂(CO)₈Pt(dppe){Bu^tC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)

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