Calculations have been carried out at the MP4SDO//6-31G* level for corner-protonated cyclopropane that show it to have an unsymmetrical π complex structure, the formal charges on the basal atoms being in the ratio 3:2; implications concerning the norbornyl cation are discussed.
M. J. S. Dewar, E. F. Healy and J. M. Ruiz, J. Chem. Soc., Chem. Commun., 1987, 943 DOI: 10.1039/C39870000943
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