The ring opening of α-cyano-α-hydroxymethyl epoxides by a solution of the complex Li2NiBr4 in tetrahydrofuran leads to α-bromo-α′-hydroxy ketones which in treatment with pyridine give good yields of α-hydroxy unsaturated aldehydes.
L. Khamliche and A. Robert, J. Chem. Soc., Chem. Commun., 1987, 1869 DOI: 10.1039/C39870001869
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