Evidence strongly suggests that the reaction of Fe3(CO)12 with CO to yield Fe(CO)5 occurs via an electron transfer catalysed pathway; a mechanism for the reaction is proposed.
S. L. Yang, C. S. Li and C. H. Cheng, J. Chem. Soc., Chem. Commun., 1987, 1872 DOI: 10.1039/C39870001872
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