Several thiocyanato- and cyano-derivatives [SnX6 –nYn]2–(X = Cl or Br, Y = NCS or CN) or the hexahalogenostannate(IV) ions [SnX6]2– have been identified in solution by 119Sn n.m.r. spectroscopy. Some isomeric configurations have been deduced by the method of pairwise interactions. The ligands in [Sn(NCS)6]2– were deduced to be N–bonded on the basis of i.r. spectroscopy.
K. B. Dillon and A. Marshall, J. Chem. Soc., Dalton Trans., 1987, 315 DOI: 10.1039/DT9870000315
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