Mesoporphyrin-II has been bridged by several 2,2′-hydroxymethyl-substituted 4,4′-bipyridine compounds. N-Methylation of the bipyridine bridge groups yielded viologen-bridged porphyrins which have unusual aggregation and fluorescence properties. An improved route to quinone-bridged porphyrins is also reported.
P. Leighton and J. K. M. Sanders, J. Chem. Soc., Perkin Trans. 1, 1987, 2385 DOI: 10.1039/P19870002385
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