A dinuclear iron(III) porphyrin–copper(II) complex with a sulphur bridge: a model for the active site of cytochrome c oxidase
Abstract
A dinuclear complex anion containing an iron(III) porphyrin and a copper(II) complex in which the metal atoms are bridged by a sulphur atom has been prepared and structurally characterized; the anion does not exhibit an e.s.r. spectrum at 4.7 K.