Differences between the rate constants and 18O distribution for the rearrangements of the β-(acyloxy)alkyl radicals (2b) and (7b) suggest that the first is a pericyclic reaction whereas the second proceeds through an anion–radical cation ion pair.
A. L. J. Beckwith and P. J. Duggan, J. Chem. Soc., Chem. Commun., 1988, 1000 DOI: 10.1039/C39880001000
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