Issue 15, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structural characterization of [Cu(SC6H4-o-SiMe3)]12, an unusual example of a ‘paddle-wheel’ dodecametallic thiolate cluster

Eric Block,   Michael Gernon,   Hyunkyu Kang,   Shuncheng Liu  and  Jon Zubieta  

Abstract

Treatment of [Cu(MeCN)4]PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC6H4-o-SiMe3, affords red-orange crystals of [Cu(SC6H4-o-SiMe3)]12, a dodecametallic thiolate cluster with a ‘paddle-wheel’ C12S12 core.

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Article information

DOI
https://doi.org/10.1039/C39880001031
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1031-1033

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Synthesis and structural characterization of [Cu(SC6H4-o-SiMe3)]12, an unusual example of a ‘paddle-wheel’ dodecametallic thiolate cluster

E. Block, M. Gernon, H. Kang, S. Liu and J. Zubieta, J. Chem. Soc., Chem. Commun., 1988, 1031 DOI: 10.1039/C39880001031

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