Reaction of S4N4O2 with PtCl2(PMe2Ph)2 in liquid ammonia gives the title compound which is the first example of a PtS2N3 ring system, as shown by X-ray crystallography; the molecule consists of a square planer PtII with a puckered PtS2N3 ring.
I. P. Parkin, A. M. Z. Slawin, D. J. Williams and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1989, 58 DOI: 10.1039/C39890000058
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