Low-valent niobium chemistry: synthesis of bent bis-arene niobium alkyl and halide complexes, half-sandwich mono-arene niobium tertiary phosphine compounds, and related studies
Abstract
The syntheses of the new compounds [Nb(η-C6H5Me)2X](X = Me, Ph, Br, I), [Nb(η-C6H5Me)(PMe3)3X (X = H, SiMe3), [Nb(η-C6H5Me)(η5-C7H9)(PMe3)], and [Nb(η-C7H7)(CO)2(PMe3)] are described.